Schwank ITBU User Manual Page 17

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Abkürzungen
2c2e = zwei-Zentren-zwei-Elektronen J = (NMR) Kopplungskonstante
B
2
Cat
2
=
Bis(catecholato)diboran k = Kilo
Ar = Aryl K = Kelvin
Ar
F
= 3,5-C
6
H
3
(CF
3
)
2
kat. = katalytisch
Ar
Cl
= 3,5-Dichlorophenyl konz. = konzentriert
tBu = tert-Butyl, C
4
H
9
L = Ligand
iBu = iso-Butyl, C
4
H
9
LUMO = Lowest Unoccupied
br = breit Molecular Orbital
bzw. = beziehungsweise m = (NMR) Multiplett
cal = Kalorien M = Metall
Cat = Catecholato, 1,2-C
6
H
4
O
2
Me = Methyl, CH
3
CCDC = Cambridge Crystallographic Mes = Mesityl, 2,4,6-Me
3
C
6
H
3
Data Centre Mes* = Supermesityl, 2,4,6-tBu
3
C
6
H
3
CHN = Elementaranalyse MHz = Megaherz
CIF = Crystallographic Information File min = Minuten
cm = Zentimeter mL = Milliliter
Cp = Cyclopentadienyl, C
5
H
5
mmol = Millimol
Cp' = Methylcyclopentadienyl, C
6
H
7
μmol = Mikromol
Cp* = Pentamethylcyclopentadienyl, C
10
H
15
mt = 2-Sulfanyl-1-methylimidazol,
Cy = Cyclohexyl, C
6
H
11
C
4
H
5
N
2
S
d = (NMR) Dublett NHC = N-heterocyclisches Carben
DCC = Dicyclohexylcarbodiimid NMR = Nuclear Magnetic Resonance,
= chemische Verschiebung (in ppm) Kernmagnetische Resonanz
Δ = Delta, Differenz Pf = Perfluorophenyl
DFT = Dichtefunktionaltheorie Ph = Phenyl, C
6
H
5
Dip = Di(isopropyl)phenyl C
6
H
3
(C
3
H
7
)
2
Pin = Pinacolato, 1,2-C
2
Me
4
O
2
Dur = 1,2,4,5-Tetramethylbenzol pm = Picometer
E = Hauptgruppenelement ppm = parts per million, 10−6
Et = Ethyl, CH
2
CH
3
iPr = iso-Propyl, C
3
H
7
etc. = et cetera, und so weiter q = (NMR) Quartett
eq. = Äquivalent R = beliebiger Rest
Fc = Ferrocenyl, {(η
5
-C
5
H
4
)Fe(η
5
-C
5
H
5
)} RT = Raumtemperatur
g = Gramm s = (NMR) Singulett
° = Grad SIMes = N,N-Dimesitylimidazolidin
h = Stunden t = (NMR)Triplett
HOMO = Highest Occupied Molecular Orbital THF = Tetrahydrofuran, C
4
H
8
O
HV = Hochvakuum usw. = und so weiter
Hz = Hertz VE = Valenzelektronen
ICy = N,N-Dicyclohexylimidazol-2-yliden vgl. = vergleiche
IMe = N,N-Dimethylimidazol-2-yliden X = Halogen
IMes = N,N-Dimesitylimidazol-2-yliden z. B. = zum Beispiel
ItBu = N,N-Di-tert-butylimidazol-2-yliden ̃ = Wellenzahl
IR = Infrarot
J = Joule
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